Daniel Smith Extra Fine Watercolor - Verditer Blue, 15 ml, Tube

Pigment Information

This color contains the following pigments:

PB28-Cobalt Blue

PW4-Zinc White

PB36-Cobalt Chromite Blue Green Spinel

Pigment Name

PB28-Cobalt Blue

Pigment Type

inorganic

Chemical Name

cobalt(II) oxide + aluminum oxide

Chemical Formula

CoO + Al2O3

Properties

Cobalt blue is a semitransparent pigment with low to moderate tinting strength. When it dries, it appears lighter and less saturated. Pigment particles are large and grainy. Differences in how the pigment is ground and mixed lead to considerable differences in its performance among various manufacturers.

Permanence

Cobalt blue is absolutely lightfast and extraordinarily stable. The stability of cobalt salts at high temperatures make them the standard for blues used in ceramics and glassware.

Toxicity

Cobalt salts are toxic. Avoid respiratory and skin contact. Soluble cobalt may cause irritation and allergic reaction through contact with skin. It is considered a possible carcinogen.

History

Since ancient times, smalt blue has been used to color glass and ceramics. Cobalt salts, which give smalt its characteristic blue color, were identified in the 18th century. Techniques for manufacturing Cobalt Blue, a chemically pure salt of cobalt and aluminum oxide, were developed in 1802.

Pigment Name

PW4-Zinc White

Pigment Type

inorganic

Chemical Name

zinc(II)-oxide

Chemical Formula

ZnO

Properties

Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.

Permanence

Zinc White has great permanence and lightfastness.

Toxicity

Zinc White is moderately toxic if ingested and slightly toxic if inhaled.

History

Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.

Pigment Name

PB36-Cobalt Chromite Blue Green Spinel

Pigment Type

inorganic

Chemical Name

Oxides of Cobalt and Chromium

Chemical Formula

Co(Al,Cr)2O4

Properties

Cobalt Chromite Blue is an opaque pigment with moderately low tinting strength.

Permanence

Cobalt salts have excellent lightfastness and temperature stability.

Toxicity

Cobalt salts are toxic when ingested or inhaled, and slightly toxic on contact with the skin. Evidence of Chromium(III) carcinogenicity is inconclusive. Chromium(III) salts appear in greenish pigments.