Grumbacher Academy Watercolor - Hooker's Green Deep Hue, 7.5 ml tube

Pigment Information

This color contains the following pigments:

PB15:4-Phthalo Blue

PG36-Phthalo Green

PY65-Hansa Yellow

PY97-Permanent Yellow

PBk6-Lamp Black

Pigment Name

PB15:4-Phthalo Blue

Pigment Type

organic

Chemical Name

copper phthalocyanine

Chemical Formula

C32H16CuN8

Properties

Phthalo Blues are pure and clean primary blues with superior covering power. They have a very high tinting strength and tend to overwhelm other pigments, but if color strength can be controlled, they make predictable mixed colors. In oil form, blues are very deep and slow drying. When mixed with other colors or if chlorine is added, Phthalo Blue quickly tends towards green. When using alone, mix with some white, as Phthalo Blue can be semi-transparent and almost black on its own. It is among the most compatible of modern colors with mineral colors and is considered more reliable than Prussian Blue, while sharing the same physical and color properties. Phthalo Blue is a good color for glazing.

Permanence

Phthalo Blues are completely lightfast and stable and are permanent for all paint uses. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Blues have no significant hazards, although those made before 1982 contained some PCBs (polychlorinated biphenyls).

History

Developed by chemists using the trade name Monastral Blue, the organic blue dyestuff now known as Phthalo Blue was presented as a pigment in November 1935 in London. Its discovery was accidental. The dark color was observed in a kettle where a dye was being made from a British dyestuff plant. The demand for such a pigment came from commercial printers who wanted a cyan to replace Prussian Blue.

Pigment Name

PG36-Phthalo Green

Pigment Type

organic

Chemical Name

polybromopolychlorinated copper(II) phthalocyanine

Chemical Formula

C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)

Properties

Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules.  Pigment PG36 differs from PG7 in that a portion of the chlorine atoms are replaced with bromine atoms, which are reactively similar, but cause a yellow shift that is especially noticeable in mixtures. Phthalo Green has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors.  This pigment most closely resembles the discontinued and toxic Verdigris.

Permanence

Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.

History

This bright blue-green was developed in 1935 and has been in use since 1938.

Pigment Name

PY65-Hansa Yellow

Pigment Type

monoazo

Chemical Formula

C18H18N4O6

Properties

This Hansa Yellow ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time.

Permanence

This Hansa Yellow has excellent lightfastness, particularly in the darker shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Pigment Name

PY97-Permanent Yellow

Pigment Type

organic, monoazo

Chemical Formula

C26H27ClN4O8

Properties

Permanent Yellow PY97 ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time. Similar in shade to Hansa Yellow 1, it offers much better fastness properties and good heat stability.

Permanence

Pigment PY97 has excellent lightfastness, particularly in the darker shades.

Toxicity

No significant acute hazards of PY97 are known, though chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow. Permanent Yellow (PY97) represents a further development of this line, with the aim of producing a yellow pigment that is suitable for exterior use.

Pigment Name

PBk6-Lamp Black

Pigment Type

inorganic

Chemical Name

carbon

Chemical Formula

C

Properties

Lamp black is a very opaque, heavily staining black pigment that does not have much covering power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures, is one of the slowest drying pigments in oils, and should not be used under other colors.

Permanence

Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.

Toxicity

Lamp Black is slightly toxic by skin contact and inhalation. It is a possible human carcinogen.

History

Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It is the black found in Egyptian murals and tomb decorations and was the most popular black for frescoing until the development of Mars Black.