Holbein Artists' Watercolor - Davy's Gray, 15 ml tube

Pigment Information

This color contains the following pigments:

PW6-Titanium White

PBr7-Burnt Sienna

PBk6-Lamp Black

Pigment Name

PW6-Titanium White

Pigment Type

inorganic

Chemical Name

titanium dioxide

Chemical Formula

TiO2

Properties

Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.

Permanence

Titanium White has excellent permanence and lightfastness.

Toxicity

Titanium dioxide is highly stable and is regarded as non-toxic.

History

Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.

Pigment Name

PBr7-Burnt Sienna

Pigment Type

earth

Chemical Name

iron oxides

Chemical Formula

Fe2O3

Properties

Burnt Sienna is a warm, mid-brown color formed by burning the yellow-brown limonite clay called Raw Sienna. It ranges from semi-opaque to semi-transparent due to the combination of its opaque, red-brown mass tone and its transparent, orangey undertone. It is an excellent mixing complement for blues and greens and creates salmon or peach colored tints when mixed with white. It can be useful for subduing bright colors and does not get chalky in dark mixtures.

Permanence

Burnt Sienna has good permanence and is considered one of the most versatile of the permanent pigments.

Toxicity

Burnt Sienna has no significant hazards.

History

Burnt Sienna has been used as a pigment since prehistoric times, but its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.

Pigment Name

PBk6-Lamp Black

Pigment Type

inorganic

Chemical Name

carbon

Chemical Formula

C

Properties

Lamp black is a very opaque, heavily staining black pigment that does not have much covering power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures, is one of the slowest drying pigments in oils, and should not be used under other colors.

Permanence

Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.

Toxicity

Lamp Black is slightly toxic by skin contact and inhalation. It is a possible human carcinogen.

History

Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It is the black found in Egyptian murals and tomb decorations and was the most popular black for frescoing until the development of Mars Black.