Schmincke Mussini Oil Color - Brownish Gray 2, 35 ml tube

Pigment Information

This color contains the following pigments:

PBr33-Zinc Iron Chromite Brown

PG36-Phthalo Green

PY42-Yellow Iron Oxide

PW4-Zinc White

Pigment Name

PBr33-Zinc Iron Chromite Brown

Pigment Type

inorganic

Chemical Name

zinc-iron-chromite spinel

Chemical Formula

ZnO + Fe203 + Cr2O3

Properties

Zinc Iron Chromite Brown is a dark reddish brown pigment that is opaque and staining.

Permanence

Zinc Iron Chromite Brown is exceptionally lightfast, heat resistant, weather resistant, and durable.

Toxicity

Zinc Iron Chromite Brown has not been identified as hazardous, but it is likely to contain impurities that are irritating to the skin or lungs. Pigment from natural ores may contain traces of heavy metals.

History

Because of its exceptional durability and heat resistance, Zinc Iron Chromite is used as a brown pigment in ceramics.

Pigment Name

PG36-Phthalo Green

Pigment Type

organic

Chemical Name

polybromopolychlorinated copper(II) phthalocyanine

Chemical Formula

C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)

Properties

Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules.  Pigment PG36 differs from PG7 in that a portion of the chlorine atoms are replaced with bromine atoms, which are reactively similar, but cause a yellow shift that is especially noticeable in mixtures. Phthalo Green has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors.  This pigment most closely resembles the discontinued and toxic Verdigris.

Permanence

Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.

History

This bright blue-green was developed in 1935 and has been in use since 1938.

Pigment Name

PY42-Yellow Iron Oxide

Chemical Name

iron(III)-oxide, hydrated

Chemical Formula

Fe2O3 • H2O

Properties

Yellow Ochre provides artists with earthtones from cream to brown. It has good hiding power, produces a quick drying paint, and can be safely mixed with other pigments. Its transparency varies widely from opaque shades to more transparent ones, which are valued for their use as glazes. If gypsum is present, Yellow Ochre is not suitable for frescoing. (See Brown Ochre, PY43.) PY42 is made from synthetic iron oxides. PY43 is made from natural iron oxide.

Permanence

Yellow Ochre has excellent permanence because ochres are some of the most permanent pigments available.

Toxicity

Yellow Ochre is non-toxic unless it contains manganese.

History

Ochre comes from the Greek word ochros, meaning pale yellow. It was one of the first pigments to be used by human beings, and evidence of its use has been found at 300,000 year old sites in France and the former Czechoslovakia.

Pigment Name

PW4-Zinc White

Pigment Type

inorganic

Chemical Name

zinc(II)-oxide

Chemical Formula

ZnO

Properties

Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.

Permanence

Zinc White has great permanence and lightfastness.

Toxicity

Zinc White is moderately toxic if ingested and slightly toxic if inhaled.

History

Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.